Modeling Polystyrene Homogeneous‐Coagulative Nucleation in Pickering Emulsion Polymerization

Advanced Core-Shell Composite Nanoparticles Through Pickering Emulsion Polymerization

Pickering emulsion templated interfacial atom transfer radical polymerization for microencapsulation.

This Article describes a new microencapsulation method based on a Pickering emulsion templated interfacial atom transfer radical polymerization (PETI-ATRP). Cationic LUDOX CL nanoparticles were coated electrostatically with an anionic polymeric ATRP initiator, poly(sodium styrene sulfonate-co-2-(2-bromoisobutyryloxy)ethyl methacrylate) (PSB), prepared by radical copolymerization of sodium styre...

Pickering Emulsion Polymerization of Styrene-co-butyl Acrylate Nanoparticles by Using Cloisite Na+ as Surfactant

Cloisite Na+was used as a solid surfactant (stabilizer) in Pickering emulsion polymerization of styrene-co-butyl acrylate in presence of oil soluble initiator, azobisisobutyronitrile (AIBN) and water soluble initiator, potassium persulfate (KPS). Fourier transform infrared (FTIR) spectrum approved the corporation of Cloisite Na+ layers within the polymer matrix. Effect of clay content was a...

Material : Aging mechanism in model Pickering emulsion

The chemicals used for the NPs synthesis are TetraEthylOrthoSilicate (TEOS), l-Arginine, chloride acid 0.1M and ethanol. They were supplied by Aldrich and used as received. High-purity deionized water (18.2 M.cm) was produced using Millipore Milli-Q Gradient system. The synthesis follows the same protocol as in our previous work [1]. It is performed in a 2000 ml reactor thermostated with hot wa...

Molecular imprinting of protein in Pickering emulsion.

A new strategy of molecular imprinting to prepare spherical hydrogels via water-in-oil Pickering emulsion polymerization was developed. The imprinted hydrogels exhibited fast adsorption kinetics and significant selectivity for the target protein.